The figure to the right shows the potential energy curves fo…
The figure to the right shows the potential energy curves for the electronic ground state and an excited state for a diatomic molecule. The horizontal lines represent vibrational states. The vibrational quantum numbers for the ground and excited electronic states are given by v” and v’ receptively. According to the Frank-Condon principle, the transition from v’=0 to which lower vibrational state would have the highest probability of emission?
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