An experiment is perfоrmed tо meаsure the mаss percent оf CаCO3(s) in eggshells. Five different samples of CaCO3(s) of known mass react with an excess of 2.0 M HCl(aq) in identical sealed, rigid reaction vessels. The pressure of the gas produced is measured with a pressure gauge attached to the reaction vessel. Since the reaction is exothermic, the reaction system is cooled to its original temperature before the pressure is recorded. The experimental data are used to create the calibrated line in the chart. The figure presents a graph consisting of five points and a straight line of best fit. The horizontal axis is labeled “Mass of C a C O 3, solid, in grams,” and the numbers 0.05 through 0.20, in increments of 0.05, are indicated. The vertical axis is labeled “Pressure of Gas Produced, in atmospheres,” and the numbers 0.02 through 0.10, in increments of 0.01, are indicated. The data represented in the graph are as follows. Note that all values are approximate. The line begins at a mass of 0.06 gram and a pressure of 0.03 atmosphere, and ends at a mass of 0.21 gram and a pressure of 0.10 atmosphere. The data points are at 0.07 gram and 0.032 atmosphere; 0.09 gram and 0.045 atmosphere; 0.14 gram and 0.068 atmosphere; 0.17 gram and 0.08 atmosphere; and 0.20 gram and 0.096 atmosphere. The experiment is repeated with an eggshell sample, and the experimental data are recorded in the table. Mass of eggshell sample 0.200 g Pressure prior to reaction 0.800 atm Pressure at completion of reaction 0.870 atm Which of the following equations best represents the species that react and the species that are produced when CaCO3(s) and HCl(aq) are combined?
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